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  1. Bonadiman, C. and (Ed.)
    McDonough, W. F. (2023) Composition of the Earth and implications for geodynamics, in C. Bonadiman and E. Rampone (eds) Chemical geodynamics of the Earth’s mantle; new paradigms, EMU Notes in Mineralogy, Chapter 1, pp 1-17. 
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    Free, publicly-accessible full text available July 1, 2024
  2. Abstract

    Potassium (K) informs on the radiogenic heat production, atmospheric composition, and volatile element depletion of the Earth and other planetary systems. Constraints on the abundance of K in the Earth, Moon, and other rocky bodies have historically hinged on K/U values measured in planetary materials, particularly comparisons of the continental crust and mid‐ocean ridge basalts (MORBs), for developing compositional models of the bulk silicate Earth (BSE). However, a consensus on the most representative K/U value for global MORB remains elusive despite numerous studies. Here, we statistically analyze a critical compilation of MORB data to determine the K/U value of the MORB source. Covariations in the log‐normal abundances of K and U establish that K is 3–7 times less incompatible than U during melting and/or crystallization processes, enabling inverse modeling to infer the K/U of the MORB source region. These comprehensive data have a mean K/U for global MORB = 13,900 ± 200 (2σm;n = 4,646), and define a MORB source region with a K/U between 14,000 and 15,500, depending on the modeled melting regime. However, this range represents strictly a lower limit due to the undefined role of fractional crystallization in these samples and challenges preserving the signatures of depleted components in the MORB mantle source. This MORB source model, when combined with recent metadata analyses of ocean island basalt (OIB) and continental crust, suggests that the BSE has a K/U value >12,100 and contains >260 × 10−6 kg/kg K, resulting in a global production of3.5 TW of radiogenic heat today and 1.5 × 1017 kg of40Ar over the lifetime of the planet.

     
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  3. Abstract

    We report the Earth's rate of radiogenic heat production and (anti)neutrino luminosity from geologically relevant short‐lived radionuclides (SLR) and long‐lived radionuclides (LLR) using decay constants from the geological community, updated nuclear physics parameters, and calculations of theβspectra. We track the time evolution of the radiogenic power and luminosity of the Earth over the last 4.57 billion years, assuming an absolute abundance for the refractory elements in the silicate Earth and key volatile/refractory element ratios (e.g., Fe/Al, K/U, and Rb/Sr) to set the abundance levels for the moderately volatile elements. The relevant decays for the present‐day heat production in the Earth (19.9 ± 3.0 TW) are from40K,87Rb,147Sm,232Th,235U, and238U. Given element concentrations in kg‐element/kg‐rock and densityρin kg/m3, a simplified equation to calculate the present‐day heat production in a rock isurn:x-wiley:ggge:media:ggge22244:ggge22244-math-0001

    The radiogenic heating rate of Earth‐like material at solar system formation was some 103to 104times greater than present‐day values, largely due to decay of26Al in the silicate fraction, which was the dominant radiogenic heat source for the first10 Ma. Assuming instantaneous Earth formation, the upper bound on radiogenic energy supplied by the most powerful short‐lived radionuclide26Al (t1/2= 0.7 Ma) is 5.5×1031 J, which is comparable (within a factor of a few) to the planet's gravitational binding energy.

     
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  4. Abstract

    The composition of the lower continental crust is well studied but poorly understood because of the difficulty of sampling large portions of it. Petrological and geochemical analyses of this deepest portion of the continental crust are limited to the study of high‐grade metamorphic lithologies, such as granulite. In situ lower crustal studies require geophysical experiments to determine regional‐scale phenomena. Since geophysical properties, such as shear wave velocity (Vs), are nonunique among different compositions and temperatures, the most informative lower crustal models combine both geochemical and geophysical knowledge. We explored a combined modeling technique by analyzing the Basin and Range and Colorado Plateau of the United States, a region for which plentiful geochemical and geophysical data are available. By comparing seismic velocity predictions based on composition and thermodynamic principles to ambient noise inversions, we identified three compositional trends in the southwestern United States that reflect three different geologic settings. The Colorado Plateau (thick crust), Northern Basin and Range (medium crust), and Southern Basin and Range (thin crust) have intermediate, intermediate‐mafic, and mafic deep crustal compositions. Identifying the composition of the lower crust depends heavily on its temperature because of the effect it has on rock mineralogy and physical properties. In this region, we see evidence for a lower crust that overall is intermediate‐mafic in composition (53.77.2 wt.% SiO) and notably displays a gradient of decreasing SiOwith depth.

     
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  5. Abstract

    Debate continues on the amount and distribution of radioactive heat producing elements (i.e., U, Th, and K) in the Earth, with estimates for mantle heat production varying by an order of magnitude. Constraints on the bulk‐silicate Earth's (BSE) radiogenic power also places constraints on overall BSE composition. Geoneutrino detection is a direct measure of the Earth's decay rate of Th and U. The geoneutrino signal has contributions from the local (40%) and global (35%) continental lithosphere and the underlying inaccessible mantle (25%). Geophysical models are combined with geochemical data sets to predict the geoneutrino signal at current and future geoneutrino detectors. We propagated uncertainties, both chemical and physical, through Monte Carlo methods. Estimated total signal uncertainties are on the order of20%, proportionally with geophysical and geochemical inputs contributing30% and70%, respectively. We find that estimated signals, calculated using CRUST2.0, CRUST1.0, and LITHO1.0, are within physical uncertainty of each other, suggesting that the choice of underlying geophysical model will not change results significantly, but will shift the central value by up to15%. Similarly, we see no significant difference between calculated layer abundances and bulk crustal heat production when using these geophysical models. The bulk crustal heat production is calculated as 7  2 TW, which includes an increase of 1 TW in uncertainty relative to previous studies. Combination of our predicted lithospheric signal with measured signals yield an estimated BSE heat production of 21.5  10.4 TW. Future improvements, including uncertainty attribution and near‐field modeling, are discussed.

     
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